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At the 2014 European Championships, Stolbova/Klimov placed fourth in the short, first in the free skate, and scored a total of 207.98 points to win the silver medal behind Volosozhar/Trankov and ahead of Bazarova/Larionov.
All three pairs were sent to the 2014 Winter Olympics.
Stolbova/Klimov decided not to compete at the 2015 World Championships in Shanghai, China, as they wanted to focus on learning new throw jumps.
Stolbova/Klimov started the 2015–16 season competing in a challenger series at the 2015 Ondrej Nepela Trophy where they won the gold medal.
Stolbova/Klimov won their first senior Grand Prix medal, bronze, at the 2012 Cup of China, and finished 5th at the 2012 Trophée Eric Bompard.
They won the bronze medal at the 2013 Russian Championships.
Third in the short program and second in the long at the 2012 Russian Championships, the pair won their first senior national medal, silver.Stolbova/Klimov were originally the first alternates for the 2012 European Championships but Alexander Smirnov had an emergency surgery and was not able to recover in time.Replacing Kavaguti/Smirnov at the event, Stolbova/Klimov set new personal bests in their short and long program to win their first European medal, bronze.Assigned to the free skate in the inaugural Olympic team event, Stolbova/Klimov placed first in their segment and Team Russia went on to win the gold medal.
In the pairs event, Stolbova/Klimov placed third in the short and advanced to second after the free skate with an overall score of 218.68 points.For the 2012–13 season, Stolbova/Klimov worked on upgrading their twist to a triple.